I don’t know what could have happened to you Nu wallet, but the screenshot you provide about Cointoolkit basically says that your private key is invalid (I can see the top input field in red), and its value is really short (for what it can be seen from the screenshot) to be a real private key. By the way, in that field you have to input your private key in WIF format.
I suggest you first paste your private key in the verify tab and click verify. Your address, details and pubkey should appear. Then you can copy that WIF private key to the signing tab and sign the transaction you were trying to sign.
Also, as @mhps says, make sure to erase the private details completely when you post screenshots. For example in that last one we can see the bottom of the private key input field, that is a huge risk for you. Someone can calculate the characters with only that bottom line of pixels and stole your NBT. The good news though is that it is too short to be valid.